壳粒磷块岩及其成矿规律   总被引：4，自引：0，他引：4  

东野脉兴  郑文忠 《矿物岩石》1992,12(2):61-69

壳粒磷块岩被作为一种独立的重要类型划分出来。壳粒磷块岩的性质从极重要的方面揭示了海相磷块岩的本质特征。本文以生物成矿论为指导,研究了扬子地块晚震旦世陡山沱期磷块岩形成的古地理,并阐述了磷块岩成矿与富集规律。  相似文献   

What controls levels of dissolved phosphate and ammonium in surface waters?   总被引：4，自引：0，他引：4  

Walter K. Dodds 《Aquatic Sciences - Research Across Boundaries》1993,55(2):132-142

Dissolved inorganic nutrient pools are small relative to particulate pools, and dissolved pools turnover rapidly. It has been observed that pools change little from day to day on the sampling scales usually employed. A simple model is presented where uptake and regeneration rates balance to cause a local steady state concentration for dissolved inorganic nutrients. Enrichment and dilution perturbation experiments with lake water support the idea of steady state nutrient concentrations. Although inorganic nutrient concentrations are often controlled by biota, the absolute concentrations present tell little about the activity of that biota.  相似文献   

基于改进全变差正则化的GPR多尺度全波形双参数同步反演          下载免费PDF全文

王珣  冯德山  王向宇 《地球物理学报》1954,63(12):4485-4501

针对探地雷达（GPR）双参数全波形反演中电导率反演精度差、双参数存在串扰现象、反演计算量大、易陷入局部极值等问题.作者将具有多参数调节功能的L-BFGS算法引入到GPR时间域全波形反演中,它避免了对Hessian矩阵的直接存储与精确求解,减小了存储量和计算量.结合参数调节因子的选取,有效减小了同步反演时介电常数与电导率的串扰影响,在不降低介电常数反演精度的前提下,提高电导率参数的反演精度.通过在反演目标函数中加载改进全变差正则化方法,提高了反演的稳定性,使目标体边缘轮廓更加清晰.首先以简单模型为例,对比了单尺度反演与多尺度串行反演策略的优劣,说明多尺度串行反演有利于逐步搜索全局最优解;而开展参数调节因子的选取实验,说明合适的参数调节因子可以有效改善介质电导率的反演精度;测试了不同正则化的反演效果,表明改进全变差正则化能提高反演稳定性,显著降低模型重构误差.最后,分别对含噪合成数据和实测数据进行了反演测试,说明本文提出的多尺度、双参数反演具有较强的鲁棒性,能提供更丰富的信息约束,重构图像界面清晰、反演效果好.  相似文献   

Calibration of diatoms along a nutrient gradient in Florida Everglades Water Conservation Area-2A, USA   总被引：2，自引：0，他引：2  

Sherri R. Cooper  Jacqueline Huvane  Panchabi Vaithiyanathan  Curtis J. Richardson 《Journal of Paleolimnology》1999,22(4):413-437

The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 g g^-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p < 0.01), with additional species differences correlated with soil C, N, Ca, and BSi.Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r² (0.86) with RMSE_boot = 218 g g^-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 g^-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 g g^-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a Disturbance Index based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.  相似文献   

Total and methylmercury in a Brazilian estuary,Rio de Janeiro     

Kehrig HA  Costa M  Moreira I  Malm O 《Marine pollution bulletin》2002,44(10):1018-1023

Guanabara Bay, in Rio de Janeiro state, is impacted by organic matter, oil and heavy metals. The present study evaluated the total mercury (THg) and methylmercury (MeHg) concentrations and the MeHg to THg ratio (%MeHg) in water samples from different points of the bay and in 245 organisms of three different trophic levels sampled between 1990 and 2000. Dissolved mercury concentration in estuarine water samples ranged from 0.72 to 5.23 ngl(-1). THg and MeHg in mussel, ranging from 11.6 to 53.5 microg THg kg(-1) wet wt. and 4.5-21.0 microg MeHg kg(-1) wet wt., varied according to sampling point and water quality. Planktivorous fish and mussel presented similar MeHg concentrations, meanwhile THg in planktivorous fish were lower than in mussel. Carnivorous fish showed higher THg and MeHg concentrations (199.5 +/- 119.3, 194.7 +/- 112.7 microg kg(-1) wet wt. respectively) than organisms from other feeding habits and lower trophic levels. There was a significant difference in the %MeHg among trophic levels: mussel presented lower MeHg percentage (33%) than planktivorous fish (54%) and carnivorous fish (98%).  相似文献   

A Basic Water Quality Model for the River Neckar: Part 2 – model‐based analysis of the oxygen budget and scenarios     

Ingo Haag 《洁净——土壤、空气、水》2006,34(6):549-559

In this paper the Basic Water Quality Model (BWQM) for the central part of River Neckar is used to analyse the oxygen budget and to assess the potentials of various measures to prevent or mitigate critical dissolved oxygen (DO) declines. It is shown that the oxygen budget is mainly governed by phytoplankton dynamics. The excessive growth of algae and the sudden break down of the resulting algal blooms may cause episodic DO depressions. Therefore, to stabilise the oxygen budget in a sustainable way, eutrophication has to be controlled within the central part of River Neckar and the upstream regions. The only feasible way to reach this goal appears to be a further drastic reduction of phosphorus emissions. In addition, it is indispensable to hold the very high standards of biochemical oxygen demand and ammonium retention at the wastewater treatment plants. A worse performance of the treatment plants would dramatically aggravate critical DO declines which may be caused by algae dynamics. As long as the oxygen budget is not completely stabilised, weir and turbine aeration can be used to mitigate DO depressions. It could be shown that the potentials of these measures suffice to keep DO at a tolerable level. However, due to the long travel times in River Neckar, it is important to start aeration up to several days before the DO minimum is reached.  相似文献   

乌梁素海沉积物中全磷的分布特征   总被引：13，自引：1，他引：13  

孙惠民  何江  高兴东  吕昌伟  樊庆云  薛红喜 《沉积学报》2006,24(4):579-584

开展了浅水草型湖泊乌梁素海沉积物中TP(全磷)的分布特征研究。结果表明,乌梁素海表层沉积物中TP含量在0.37~0.99 g/kg之间变化,平均值为0.75 g/kg;水平分布上,TP含量呈现从湖区四周向湖心递减的变化趋势,大部分湖区已具有生态毒性效应,并对湖区底栖生物群落和生态环境构成了较大威胁;垂向上,尽管沉积物中TP含量有所波动,但0~10 cm的表层沉积物中TP含量均随深度增加而递减,揭示了近年来人类活动的加剧对乌梁素海沉积物中磷累积的重大影响;实验得出了粉砂、粘土粒级>极细砂粒级>细砂粒级>中砂以上粒级的TP含量序列,各粒级对TP的吸附贡献率由吸附能力和质量百分比共同控制;磷的沉积对乌梁素海富营养化进程有深远影响。  相似文献   

沉水植物黑藻对上覆水中各形态磷浓度的影响   总被引：16，自引：2，他引：16  

王圣瑞  金相灿  赵海超  崔哲  颜昌宙  步青云  楚建周  周小宁 《地球化学》2006,35(2):179-186

室内模拟研究了沉水植物黑藻对上覆水中不同形态磷浓度的影响及其季节性变化,并从沉水植物生长、间隙水和碱性磷酸酶活性(APA)三方面进行了讨论,进一步揭示磷在浅水湖泊水-沉积物界面的交换机理。结果表明,在本研究条件下,上覆水中各形态磷以溶解性总磷(DTP)为主,其他形态磷浓度变异较大,黑藻降低了上覆水中总磷(TP)、溶解性活性磷(SRP)和DTP浓度,也降低了DTP和SRP占总磷的比例,从而使颗粒态总磷(PP)和溶解性有机磷(DOP)占总磷比例升高。黑藻主要通过吸收上覆水中的磷和抑止沉积物、上覆水中APA使上覆水中各形态磷浓度保持较低水平,其中对SRP和DTP浓度的影响更明显。上覆水中各形态磷浓度呈现明显的季节性变化。在7～8月,TP、SRP和DTP浓度呈下降趋势,并在8月达到最低值;9～10月间有所升高,但仍然维持在较低水平,不同采样时间存在波动。  相似文献   

水库现代沉积过程沉积磷的早期成岩作用模型研究   总被引：2，自引：0，他引：2  

朱俊  王雨春  万国江  刘丛强 《矿物学报》2006,26(3):296-302

在沉积磷形态分析、孔隙水化学、核素计年以及吸附解吸实验等的基础上,运用一维“反应-平流-扩散”模型,研究了红枫湖现代沉积过程中磷的沉积改造。结果表明:红枫湖现代沉积过程中,有机态磷的矿化分解和铁结合态磷的络合/溶解,是控制沉积物磷迁移转化动力学的主要机制。沉积物-水界面附近有机磷的快速降解,可能克服沉积界面上铁氧化物对溶解磷的吸附缓冲,而形成向水体的磷酸盐迁移通量;自生磷灰石的沉积改造相对不明显,沉积磷向稳定形态含磷矿物(钙氟磷灰石)的转化过程同样不能影响红枫湖现代沉积过程中磷转化的质量平衡。  相似文献   

随机扩散水质模型研究          下载免费PDF全文

彭勤文 《水科学进展》2006,17(1):113-115

考虑湖泊中影响总磷沉积过程的众多生态因子的变化过程,假定湖泊中总磷沉积过程由标准布朗运动驱动,建立了一个总磷浓度的随机扩散方程,推广确定性富营养化Vollenweider水质模型为随机扩散模型,获得了总磷浓度过程的解析解,进而求出了总磷浓度过程的均值和方差,指出了一种依据沉积系数调控湖泊中总磷浓度的方法。模型被应用于巢湖总磷浓度过程的模拟。  相似文献